HIPC-1: High Purity Carbon Certified Reference Material for Mass Fraction of Carbon, Carbon Isotope Delta and Elemental Impurities

Alternative title

HIPC-1 : Matériau de référence certifié de carbone de pureté élevée pour la fraction massique du carbone, le delta isotopique du carbone et les impuretés élémentaires

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File	Format	Size
View certificate (English)	PDF	850 KiB
View certificate (French)	PDF	751 KiB
View Safety Data Sheet (English)	PDF	101 KiB
View Safety Data Sheet (French)	PDF	233 KiB
View dataset	CSV	68 KiB
View dataset for impurities	CSV	16 KiB

DOI

Resolve DOI: https://doi.org/10.4224/crm.2022.hipc-1

Author

Search for: Chartrand, Michelle M.G.¹ORCID identifier: https://orcid.org/0000-0003-3398-7246; Search for: Methven, Brad¹; Search for: Simon, Adrian¹; Search for: Middlestead, Paul²; Search for: Hélie, Jean-Francois³ORCID identifier: https://orcid.org/0000-0002-0994-5620; Search for: Grinberg, Patricia¹ORCID identifier: https://orcid.org/0000-0002-1167-6474; Search for: Pagliano, Enea¹ORCID identifier: https://orcid.org/0000-0001-9755-8737; Search for: Meija, Juris¹ORCID identifier: https://orcid.org/0000-0002-3349-5535; Search for: Yang, Lu¹ORCID identifier: https://orcid.org/0000-0002-6896-8603; Search for: Mester, Zoltan¹ORCID identifier: https://orcid.org/0000-0002-2377-2615

Affiliation

National Research Council of Canada
Ján Veizer Stable Isotope Laboratory, University of Ottawa
Geotop, Université du Québec à Montréal

Format

3D, Material

Material type

High-purity material

Subject

Canadian reference material; HIPC-1; carbon; elemental impurities; carbon isotopes

Abstract

HIPC-1 is a high purity carbon Certified Reference Material (CRM). A unit of HIPC-1 consists of approximately 0.25 g of high purity carbon rod. This material is intended as a primary standard for the determination of the mass fraction of carbon, and for carbon isotope delta measurements.

Analytes

View analytes

Analyte	Quantity	Value	Expanded uncertainty	Unit	Type
carbon	mass fraction	0.99989	0.00027	kg/kg	certified
¹³C/¹²C	isotope delta vs VPDB-LSVEC	-26.32	0.11	permille	certified
lithium	mass fraction	<8	19	µg/kg	certified
beryllium	mass fraction	<3	8	µg/kg	certified
boron	mass fraction	1500	1800	µg/kg	certified
nitrogen	mass fraction	21000	211000	µg/kg	certified
oxygen	mass fraction	45000	139000	µg/kg	certified
fluorine	mass fraction	<4200	10800	µg/kg	certified
sodium	mass fraction	680	3200	µg/kg	certified
magnesium	mass fraction	<360	200	µg/kg	certified
aluminium	mass fraction	340	1000	µg/kg	certified
silicon	mass fraction	5700	78400	µg/kg	certified
phosphorus	mass fraction	90	490	µg/kg	certified
sulfur	mass fraction	6700	6700	µg/kg	certified
chlorine	mass fraction	2100	2100	µg/kg	certified
potassium	mass fraction	<2400	1400	µg/kg	certified
calcium	mass fraction	14100	24000	µg/kg	certified
scandium	mass fraction	<14	8	µg/kg	certified
titanium	mass fraction	<86	51	µg/kg	certified
vanadium	mass fraction	<6	4	µg/kg	certified
chromium	mass fraction	<1700	1000	µg/kg	certified
manganese	mass fraction	<60	39	µg/kg	certified
iron	mass fraction	600	1800	µg/kg	certified
cobalt	mass fraction	<11	7	µg/kg	certified
nickel	mass fraction	<28	19	µg/kg	certified
copper	mass fraction	6800	32600	µg/kg	certified
zinc	mass fraction	<350	730	µg/kg	certified
gallium	mass fraction	<57	34	µg/kg	certified
germanium	mass fraction	<40	120	µg/kg	certified
arsenic	mass fraction	90	330	µg/kg	certified
selenium	mass fraction	<150	90	µg/kg	certified
bromine	mass fraction	<170	430	µg/kg	certified
rubidium	mass fraction	<70	60	µg/kg	certified
strontium	mass fraction	<100	70	µg/kg	certified
yttrium	mass fraction	<6	3	µg/kg	certified
zirconium	mass fraction	<10	120	µg/kg	certified
niobium	mass fraction	<14	35	µg/kg	certified
molybdenum	mass fraction	<67	40	µg/kg	certified
ruthenium	mass fraction	<130	330	µg/kg	certified
rhodium	mass fraction	<50	510	µg/kg	certified
palladium	mass fraction	<150	380	µg/kg	certified
silver	mass fraction	<24	61	µg/kg	certified
cadmium	mass fraction	<13	6	µg/kg	certified
indium	mass fraction	<13	33	µg/kg	certified
tin	mass fraction	<110	270	µg/kg	certified
antimony	mass fraction	<35	28	µg/kg	certified
tellurium	mass fraction	<40	360	µg/kg	certified
iodine	mass fraction	<9	22	µg/kg	certified
caesium	mass fraction	<39	22	µg/kg	certified
barium	mass fraction	<33	18	µg/kg	certified
lanthanum	mass fraction	<5	6	µg/kg	certified
cerium	mass fraction	<11	9	µg/kg	certified
praseodymium	mass fraction	<9	24	µg/kg	certified
neodymium	mass fraction	<35	89	µg/kg	certified
samarium	mass fraction	<47	24	µg/kg	certified
europium	mass fraction	<12	11	µg/kg	certified
gadolinium	mass fraction	<39	19	µg/kg	certified
terbium	mass fraction	<9	24	µg/kg	certified
dysprosium	mass fraction	<35	21	µg/kg	certified
holmium	mass fraction	<9	24	µg/kg	certified
erbium	mass fraction	<28	72	µg/kg	certified
thulium	mass fraction	<10	25	µg/kg	certified
ytterbium	mass fraction	<30	76	µg/kg	certified
lutetium	mass fraction	<10	25	µg/kg	certified
hafnium	mass fraction	<62	50	µg/kg	certified
tantalum	mass fraction	<300	770	µg/kg	certified
tungsten	mass fraction	<91	50	µg/kg	certified
rhenium	mass fraction	<70	170	µg/kg	certified
osmium	mass fraction	<160	400	µg/kg	certified
iridium	mass fraction	<110	280	µg/kg	certified
platinum	mass fraction	<60	170	µg/kg	certified
gold	mass fraction	<180	460	µg/kg	certified
mercury	mass fraction	<310	160	µg/kg	certified
thallium	mass fraction	<26	67	µg/kg	certified
lead	mass fraction	<60	50	µg/kg	certified
bismuth	mass fraction	<16	42	µg/kg	certified
thorium	mass fraction	<45	27	µg/kg	certified
uranium	mass fraction	<45	25	µg/kg	certified

Publication date

2022-09-01

Publisher

National Research Council of Canada

Access condition

Please visit http://nrc-cnrc.gc.ca/crm to obtain the material
http://nrc-cnrc.gc.ca/crm

References

View items (12)

Guide to the expression of uncertainty in measurement (GUM) (1 September 2008). https://www.bipm.org/en/publications/guides.
Coplen, Tyler B., Willi A. Brand, Matthias Gehre, Manfred Gröning, Harro A. J. Meijer, Blaza Toman, and R. Michael Verkouteren. ‘New Guidelines for δ13C Measurements’. Analytical Chemistry 78, no. 7 (16 February 2006): 2439–41. https://doi.org/10.1021/ac052027c.
Grinberg, Patricia, Bradley A. J. Methven, Katarzyna Swider, and Zoltan Mester. ‘Determination of Metallic Impurities in Carbon Nanotubes by Glow Discharge Mass Spectrometry’. ACS Omega 6, no. 35 (25 August 2021): 22717–25. https://doi.org/10.1021/acsomega.1c03013.
Sturgeon, R E, B Methven, S N Willie, and P Grinberg. ‘Assignment of Purity to Primary Metal Calibrants Using Pin-Cell VG 9000 Glow Discharge Mass Spectrometry: A Primary Method with Direct Traceability to the SI International System of Units?’ Metrologia 51, no. 5 (25 June 2014): 410–22. https://doi.org/10.1088/0026-1394/51/5/410.
Brand, Willi A., Tyler B. Coplen, Jochen Vogl, Martin Rosner, and Thomas Prohaska. ‘Assessment of International Reference Materials for Isotope-Ratio Analysis (IUPAC Technical Report)’. Pure and Applied Chemistry 86, no. 3 (20 March 2014): 425–67. https://doi.org/10.1515/pac-2013-1023.
Chartrand, Michelle M.G., Juris Meija, Paramee Kumkrong, and Zoltan Mester. ‘Three Certified Sugar Reference Materials for Carbon Isotope Delta Measurements’. Rapid Communications in Mass Spectrometry 33, no. 3 (15 January 2019): 272–80. https://doi.org/10.1002/rcm.8357.
International Atomic Energy Agency (2007) NBS 22, IAEA-CH-3, IAEA-CH-6, IAEA-CH-7, USGS24 reference sheet (3 August 2007). https://nucleus.iaea.org/sites/ReferenceMaterials/Shared%20Documents/ReferenceMaterials/StableIsotopes/NBS-22/RS_NBS22_USGS24_IAEA-CH-3-6-7.pdf.
US Geological Survey (2019) Report of Stable Isotopic Composition Reference Materials USGS61, USGS62 and USGS63 (Hydrogen, Carbon and Nitrogen Isotopes in Caffeine) (2 December 2019). https://isotopes.usgs.gov/lab/referencematerials/USGS61-USGS62-USGS63.pdf.
US Geological Survey (2019) Report of Stable Isotopic Composition Reference Materials USGS64, USGS65, USGS66 (Carbon and Nitrogen Isotopes in Glycine) (2 December 2019). https://isotopes.usgs.gov/lab/referencematerials/USGS64-USGS65-USGS66.pdf.
Assonov, Sergey, Manfred Groening, Ales Fajgelj, Jean‐Francois Hélie, and Claude Hillaire‐Marcel. ‘Preparation and Characterisation of IAEA‐603, a New Primary Reference Material Aimed at the VPDB Scale Realisation for δ13C and δ18O Determination’. Rapid Communications in Mass Spectrometry 34, no. 20 (27 August 2020). https://doi.org/10.1002/rcm.8867.
Assonov, Sergey, Ales Fajgelj, Jean‐François Hélie, Colin Allison, and Manfred Gröning. ‘Characterisation of New Reference Materials IAEA‐610, IAEA‐611 and IAEA‐612 Aimed at the VPDB δ13C Scale Realisation with Small Uncertainty’. Rapid Communications in Mass Spectrometry 35, no. 7 (18 February 2021). https://doi.org/10.1002/rcm.9014.
Hélie, Jean-François, Agnieszka Adamowicz-Walczak, Paul Middlestead, Michelle M.G. Chartrand, Zoltán Mester, and Juris Meija. ‘Discontinuity in the Realization of the Vienna Peedee Belemnite Carbon Isotope Ratio Scale’. Analytical Chemistry 93, no. 31 (27 July 2021): 10740–43. https://doi.org/10.1021/acs.analchem.1c02458.

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Collection

Canadian Reference Materials and Methods

Record identifier

d3f39bec-e3b5-412f-9e61-306655d19603

Record created

2022-09-20

Record modified

2025-05-23

Date modified:: 2025-06-20